And this has a built-in frustration, a tension in the system. So it moves around, it squirms until a shape is formed. And the natural self-assembled shape that is formed is nanoscale, it’s regular, it’s periodic, and it’s long range, which is exactly what we need for our transistor arrays.
So we can use molecular engineering to design different shapes of different sizes and of different periodicities. So for example, if we take a symmetrical molecule, where the two polymer chains are similar length, the natural self-assembled structure that is formed is a long, meandering line, very much like a fingerprint.
And the width of the fingerprint lines and the distance between them is determined by the lengths of our polymer chains but also the level of built-in frustration in the system. And we can even create more elaborate structures if we use unsymmetrical molecules, where one polymer chain is significantly shorter than the other.
And the self-assembled structure that forms in this case is with the shorter chains forming a tight ball in the middle, and it’s surrounded by the longer, opposing polymer chains, forming a natural cylinder. And the size of this cylinder and the distance between the cylinders, the periodicity, is again determined by how long we make the polymer chains and the level of built-in frustration.
So in other words, we’re using molecular engineering to self-assemble nanoscale structures that can be lines or cylinders the size and periodicity of our design.
We’re using chemistry, chemical engineering, to manufacture the nanoscale features that we need for our transistors. But the ability to self-assemble these structures only takes us half of the way, because we still need to position these structures where we want the transistors in the integrated circuit.
But we can do this relatively easily using wide guide structures that pin down the self-assembled structures, anchoring them in place and forcing the rest of the self-assembled structures to lie parallel, aligned with our guide structure.
For example, if we want to make a fine, 40-nanometer line, which is very difficult to manufacture with conventional projection technology, we can manufacture a 120-nanometer guide structure with normal projection technology, and this structure will align three of the 40-nanometer lines in between. So the materials are doing the most difficult fine patterning.
And we call this whole approach “directed self-assembly.” The challenge with directed self-assembly is that the whole system needs to align almost perfectly, because any tiny defect in the structure could cause a transistor failure.
And because there are billions of transistors in our circuit, we need an almost molecularly perfect system. But we’re going to extraordinary measures to achieve this, from the cleanliness of our chemistry to the careful processing of these materials in the semiconductor factory to remove even the smallest nanoscopic defects.
So directed self-assembly is an exciting new disruptive technology, but it is still in the development stage.
But we’re growing in confidence that we could, in fact, introduce it to the semiconductor industry as a revolutionary new manufacturing process in just the next few years. And if we can do this, if we’re successful, we’ll be able to continue with the cost-effective miniaturization of transistors, continue with the spectacular expansion of computing and the digital revolution.
And what’s more, this could even be the dawn of a new era of molecular manufacturing. How cool is that?