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Here is the full transcript of Nai-Chang Yeh’s TEDx Talk: A New World Composed of Graphene-Based Technology at TEDxTaoyuan conference.
Carbon is an essential element of life, and is also one of the most abundant elements on earth. Carbon occupies a place in the second row of the periodic table, right above silicon.
A single carbon atom consists of 6 protons, 6 or 7 neutrons, and 6 electrons. A well-known example of carbon is the tip of pencils. The tip of pencils consists of graphite, which refers to a collection of carbon atoms, layers of carbon atoms. Each layer of the carbon atoms forms a honeycomb structure which is called graphene. Although scientists knew that graphene layers are the constituents for graphite, for years they were not sure whether a monolayer of graphene could be isolated in nature.
Until 2004, when two British physicists finally demonstrated that a single atomic layer of graphene can be isolated and stabilized in nature. These two physicists, Dr Novoselov and Dr Geim of Manchester University, not only demonstrated that graphene can be isolated and stabilized in nature, they also carried out detailed studies of the properties of graphene. They found that graphene exhibited very interesting and unique properties that could be promising for a wide range of applications. Therefore, their research ignited great excitement throughout the world.
So, what are the unique properties of graphene that makes it so special? Graphene, actually, is both electrically and thermally highly conductive, so electrons on graphene can move like massless particles ballistically across the surface of graphene without being scattered. Graphene is very thin and optically transparent, so light can penetrate through graphene without being reflected.
The edges of graphene also exhibit very interesting properties that can be functionalized for chemical applications. The tiny honeycomb structure of graphene can only allow electrons and protons to penetrate through, so, for this reason, graphene can be used for filtering of chemical elements.
Moreover, graphene is mechanically flexible and 200 times stronger than steel. You can imagine, with these unique properties, many applications become possible. For instance, the excellent electrical and thermal conductivity, combining with the optical transparency, make it possible for graphene to be applied to nanoelectronics in integrated circuits, to optoelectronic components like solar cells, light-emitting diodes, lasers and display panels.
The flexible and strong mechanical properties of graphene can be used for lightweight, high-strength materials applicable to things such as transportation vehicles, airplanes. The excellent chemical filtering capabilities of graphene makes it possible for graphene to be used in desalination, detoxification, chemical sensing, DNA sequencing and even delivery of medicine.
The edges of graphene are very interesting also. In fact, there are two distinctly different types of edges for graphene. One is called the armchair edges, the other is called the zigzag edges. The zigzag edges usually are chemically more reactive and so can be functionalized for all kinds of chemical applications. If you take a piece of graphene and cut it into small stripes, then you have graphene nanoribbons.
You can have either armchair or zigzag graphene nanoribbons. All of these nanoribbons have very large edge-to-area ratios, and so they can be very good, very effective, for charging and discharging. For this reason, graphene nanoribbons can be used in supercapacitors, batteries for energy storage. Despite all these wonderful properties of graphene, there are major challenges before we can fully realize the potential of graphene. In particular, we need to develop reliable large-scale production of graphene with high quality and low cost.
Currently, there are three typical ways of making graphene. The first one is called mechanical exfoliation from graphite. What it is, is actually involving the use of adhesive tapes, or a Scotch tape that you’re familiar with. You take a piece of Scotch tape, press it against graphite, and you peel it off. Then you get tiny flakes of graphite.
Then you keep repeating the process until you hopefully get little, little flakes of graphene that can be monolayer or bilayer or multilayers. As you can imagine, this is a method that’s labor-intensive and very slow in production. It’s not scalable: you have no control of the quality and size of the graphene samples. But this was the initial method used by the two Nobel laureates.
A second method is based on chemical reduction, which utilizes very toxic chemicals to oxidize graphite into graphite oxide, and then chemically reduces graphite oxide into tiny flakes of graphene. This method, again, is environmentally unfriendly, and also the produced graphene flakes are uncontrollable in size, number of layers and quality. As a matter of fact, most of these graphene flakes consist of lots and lots of impurities.
The third method is called chemical vapor deposition, which involves using multistep, long-term processes of growing graphene on metals such as copper or nickel. The growth process involves very, very high temperature — 1,000 degrees centigrade. Typically, this method can produce sufficiently large areas of graphene sheets, and the quality can be reasonable if you take a lot of time to go through many steps to produce the material.
Overall this process is very expensive. The other problem is that it’s incompatible with most device fabrications. And so, as you can see, all these three methods are not ideal for fully realizing the potential of graphene. To overcome these problems, we recently developed a new method, which is called plasma-assisted, chemical vapor deposition, or PECVD. This process takes place at room temperature, in a single step, and only takes a few minutes, and there we produce excellent quality of graphene.
The idea is the following: We take a piece of copper. The copper surface is very reactive and so usually is covered with oxide. We subject the copper piece to hydrogen plasma and other radicals like cyan. And then once we clean up the surface of copper, try to get rid of all of the copper oxide, we flow methane gas through this highly reactive copper. And so the copper surface will rip apart the chemical bonds between carbon and hydrogen, and then allow carbon to nucleate on the surface of the copper and turn into graphene.
And with this approach, we can actually grow very large areas of graphene in a very short time, which is of excellent quality, electrically, structurally and mechanically. And here I just show you an example from the images we took using our scanning tunneling microscope on our PECVD-grown graphene.
As you can see, at the small scale, you can visualize the honeycomb structure of carbon. We can also modify our process a little bit so that not only can we grow large sheets of graphene, we can also grow graphene nanoribbons. This little modification involves adding additional precursor molecules so that graphene can also grow vertically on the surface of the copper and turn into graphene nanoribbons.